00-091

Cover Page/Proposal Summary

Planetary Atmospheres

Cover Page/Proposal Summary

ROSS-99    NRA 99-OSS-01

Date Due: 5/3/99

NASA PROCEDURE FOR HANDLING PROPOSALS

This proposal shall be used and disclosed for evaluation purposes only, and a copy of this Government notice shall be applied to any reproduction or abstract thereof. Any authorized restrictive notices that the submitter places on this proposal shall also be strictly complied with. Disclosure of this proposal for any reason outside the Government evaluation purposes shall be made only to the extent authorized by the Government.

Proposal Type: New Proposal

Proposal Category: Atmosphere Structures and Particles

Major Equipment Proposal? No

Do you intend to submit an Education/Public Outreach (E/PO) proposal? Yes

Proposal Title:
Laboratory Measurement of the Formation, Photolysis, and Spectral Properties of Giant-Planet Cloud Condensates

Abbreviated Proposal Title:
Laboratory Measurements of Jovian Cloud Materials

Principal Investigator:
Dr. Robert Carlson
Earth and Space Sciences Division Mail Stop 183-601
Jet Propulsion Lab.
4800 Oak Grove Drive
Pasadena, CA 91109-8099
Phone: 818-354-2648   Fax: 818-393-3218   E-mail: rcarlson@issac.jpl.nasa.gov

SignatureDate
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Co-Investigators and Collaborators:
Type    Name    Affiliation    E-mail
Sci Co-I   Mr. Mark S Anderson   JPL   msanders@jpl.na sa.gov
Sci Co-I   Prof. Fred W. Taylor   Oxford Univ.   fwt@atm.ox.ac.uk
Sci Co-I   Prof. Patrick J. Irwin   Oxford Univ.   irwin@atm.ox.ac.uk


Proposal Summary:

The clouds of the Jovian planets may be more complex than considered in current models. Species such as ammonium hydrosulfide, ammonium sulfide, ammonium polysulfide and others are possible, but no thermodynamic data exists for them at the required temperatures. Further, the spectral properties of the sulfide and polysulfides are unknown. The primary goal is to study the products formed from the binary system of NH3 and H2S as functions of temperature and partial pressure, simulating Jovian conditions. Such products include NH4HS, (NH4)2S, (NH4)2Sx, (NH4)2S*xNH4HS and (NH4)2S*2NH3. Species identification, rates of formation, and spectral properties (0.2 to 50 microns) will be obtained for these products. Reference spectra will also be obtained using independent chemical synthesis. We will also irradiate the products with ultraviolet and visible radiation (spectrally filtered) and determine the photolysis products, their spectra, rates of formation, and the production of cloud colors. A systematic and methodical two-year program is proposed. It uses existing equipment The project involves two US investigators and the atmospheric research group from Oxford University. A research student from the University will participate at JPL for extended periods, providing large cost savings to NASA.